Correlation capillary zone electrophoresis, a novel technique to decrease detection limits

End-column detection for capillary zone electrophoresis.

(29) Pszenny, A. A. P.: Harvey, G. R.; Brown, C. J.; Lang, R. F.; Keene, W. (21) Hendbook of ChemistryandPhysics, 56th ed.; CRC Press: Cleveland, OH, 1975. (22) Van Wijk, R. J. Chromatogr. Sci. 1970, 8 , 418-420. (23) Bertsch, W.: Chang, R. C.; Zlatkis, A. J. Chromatogr. Sei. 1974. 72, 175-182. (24) Butler, L. D.; Burke, M. F. J. Chromatogr. Sci. 1976, 74, 117-122. (25) Lang, R. F. Anal. Chem. ...

Two-dimensional capillary electrophoresis: capillary isoelectric focusing and capillary zone electrophoresis with laser-induced fluorescence detection.

CIEF and CZE are coupled with LIF detection to create an ultrasensitive 2-D separation method for proteins. In this method, two capillaries are joined through a buffer-filled interface. Separate power supplies control the potential at the injection end of the first capillary and at the interface; the detector is held at ground potential. Proteins are labeled with the fluorogenic reagent Chromeo...

Capillary zone electrophoresis pdf

HUMIC SUBSTANCES Capillary Zone Electrophoresis

Humic substances (HS) which are widespread in the soil, present structural complexity and polyelectrolyte properties. Many techniques and methods have been used to obtain more information about them, as reviewed by Davies and Ghabbour in 1999. The characterization of HS has been the focus of intense research for many years because the organic matter in soil contributes to the quality of the soi...

Determination of histamine by capillary zone electrophoresis with amperometric detection.

Capillary zone electrophoresis was employed for the determination of histamine using end-column amperometric detection with a carbon fiber microelectrode, at a constant potential. The optimum conditions of separation and detection were 10 mmol/L phosphate buffer, pH 5.6 for the buffer solution, 15 kV for the separation voltage, and 1.35 V (versus SCE) for the detection potential. The linear ran...